There are various methods to produce graphene materials, such as mechanical exfoliation of graphite, liquid-phase exfoliation and reduction of graphene oxide (GO), each with its own set of advantages and disadvantages. Chemical vapor deposition (CVD) is a method of producing graphene that has attracted much attention in the last decade and despite several shortcomings, is considered a leading approach to manufacture graphene, especially for applications like high-performance electronics and sensors, as it can yield high quality graphene sheets with a low defect count and good uniformity.
The CVD process
Generally speaking, the CVD method is based on gaseous reactants that are deposited on a substrate. The graphene is grown on a metallic surface like Cu, Pt or Ir, after which it can be separated from the metal and transferred to specifically-required substrates. When the gases contact the substrate inside the heated reaction chamber, a reaction occurs that creates a film of material on the substrate. The process can be simply explained as carbon-bearing gases that react at high temperatures (900–1100 °C) in the presence of a metal catalyst, which serves both as a catalyst for the decomposition of the carbon species and as a surface for the nucleation of the graphene lattice.
As was mentioned before, conditions like temperature, pressure, duration of time and many more can have a significant influence on the process and so must be carefully monitored.
Advantages and disadvantages
CVD can yield high quality graphene, with common characteristics that may include high homogeneity, imperviousness, high purity, fine grains, good control over layer number and more. However, CVD also comes with several disadvantages - namely a relatively high price of the equipment, toxic gaseous by-products and, as stated before, it is a rather sensitive process that is easily influenced by parameter changes. It is important to note that while CVD is a rather expensive method compared to other methods to produce lower-quality graphene, it is still probably the best way (to date) to acquire high quality graphene, since other ways to do that are even more expensive or complicated.
In addition, the separation (or exfoliation) of graphene from the substrate is known as challenging and it is tricky to accomplish without damaging the structure of the graphene or affecting the properties of the material. Another harrowing task is the creation of a uniform layer of graphene on a substrate, something that is continuously proving to not be easy at all.
Some approaches were and are still being developed to overcome this issue, like modifying the concentration of gases and incorporating spin coating methods, but this remains a challenge. However, despite these challenges, it is important to note that CVD is widely considered as an important and promising method to produce graphene, which is already in use, and will probably be even more so in the future, once further advancements are made. It is noteworthy that CVD is already a dominant manufacturing route for many other nanomaterials, and will assumably be in extremely common use once progress is made to resolve the issues that are currently hindering its acceptance.
While using the CVD method to produce graphene is definitely one the leading approaches in the world, it is still hindered by the challenges mentioned above. Thus, it is currently mostly limited to relatively small volumes and mainly restricted to R&D and academic uses.
However, graphene sheets produced via CVD methods are used in several applications like sensors, touch screens and heating elements. It is believed that once better answers are found to the questions of price and handling of CVD graphene, many more applications will start to appear.
Looking to buy CVD graphene sheets?
If you are interested in buying CVD graphene sheets, check out the Graphene Catalog that lists various CVD produced graphene sheets from several producers.
The latest CVD graphene news:
Korea-based Charmgraphene has started to mass produce CVD graphene, using its proprietary roll-to-roll process.
CharmGraphene's R2R production system can produce 2 meters of CVD graphene per minute (maximum width 300 mm). According to CharmGraphene, its current CVD graphene capacity is about 8,000 sqm per month. The company says it uses use 6 um thick copper foil which reduces copper foil etching time dramatically compare to 35 um thickness copper foil used by other companies.
Today we published new versions of all our graphene market reports. Graphene-Info provides comprehensive niche graphene market reports, and our reports cover everything you need to know about these niche markets. The reports are now updated to July 2021.
- The advantages using graphene batteries
- The different ways graphene can be used in batteries
- Various types of graphene materials
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- Detailed specifications of some graphene-enhanced anode material
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The report package provides a good introduction to the graphene battery - present and future. It includes a list of all graphene companies involved with batteries and gives detailed specifications of some graphene-enhanced anode materials and contact details into most graphene developers. Read more here!
South Korea's leading steel group, POSCO, will reportedly lead the creation of a graphene ecosystem in the southeastern industry port of Pohang in cooperation with research groups and Graphene Square, to meet the growing demand in the fields of semiconductors, electronics, electric batteries and composites.
POSCO said it has signed a business agreement with Pohang City, the Research Institute of Industrial Science & Technology (RIST), Pohang University of Science and Technology (POSTECH), and Graphene Square, which is developing systems for the mass production of large-scale graphene synthesized by chemical vapor deposition (CVD).
Graphene-Info is proud to present our new market report, The CVD Graphene Market Report. This market report, brought to you by the world's leading graphene industry experts, is a comprehensive guide to CVD graphene materials, the current industry and market status, and the promising applications in optoelectronics, bio-sensors, thermal solutions and more.
Reading this report, you'll learn all about:
- How does CVD graphene differ from other graphene types
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The report also provides a list of prominent CVD graphene research activities, a list of all CVD graphene developers and their products, datasheets and brochures from over 10 different CVD graphene makers and more.
South Korea-based Graphene Square, developer and distributor of graphene materials and films, has announced that it is preparing for an IPO to fuel global expansion. It will select the underwriter this year and plans its Kosdaq listing in 2022 through the Technology Special Listing program, a system introduced in 2005 to allow promising startups to list the local bourse based on a technology evaluation conducted by Korea Exchange-designated institutions.
Graphene Square’s competitive edge is said to be found in its proprietary chemical vapor deposition (CVD) method used for the production of graphene. The method is based on the research of Professor Hong Byung-hee of Seoul National University on the synthesis of large-area graphene. In fact, Graphene Square itself was established in 2012 as a spin-off of chemistry professor Hong Byung-hee’s lab at Seoul National University.