Researchers at MIT and Israel's Technion have used graphene to devise a new way of enhancing the interactions between light and matter, in a work that could someday lead to more efficient solar cells that collect a wider range of light wavelengths, and new kinds of lasers and light-emitting diodes (LEDs) that could have fully tunable color emissions.
The basic principle behind the new approach is a way to get the momentum of light particles (photons) to more closely match that of electrons, which is normally much greater. This huge difference in momentum normally causes these particles to interact very weakly; bringing their momenta closer together enables much greater control over their interactions, which could enable new kinds of basic research on these processes as well as a host of new applications, the researchers say.
The researchers explain that while silicon is an important substance as the basis for most present-day electronics, it is not well-suited for applications that involve light, such as LEDs and solar cellsâeven though it is currently the principal material used for solar cells despite its low efficiency. Improving the interactions of light with an important electronics material like silicon could be an important step toward integrating photonicsâdevices based on manipulation of light wavesâwith electronic semiconductor chips.
Most people looking into this problem have focused on the silicon itself, but "this approach is very differentâwe're trying to change the light instead of changing the silicon." The team adds that "people design the matter in light-matter interactions, but they don't think about designing the light side."
One way to do that is by slowing down, or shrinking, the light enough to drastically lower the momentum of its individual photons, to get them closer to that of the electrons. In their theoretical study, the researchers showed that light could be slowed by a factor of a thousand by passing it through a kind of multilayered thin-film material overlaid with a layer of graphene. The layered material, made of gallium arsenide and indium gallium arsenide layers, alters the behavior of photons passing through it in a highly controllable way. This enables the researchers to control the frequency of emissions from the material by as much as 20 to 30%, says Yaniv Kurman of Technion, who is the paper's lead author.
The interaction of a photon with a pair of oppositely charged particlesâsuch as an electron and its corresponding "hole"âproduces a quasiparticle called a plasmon, or a plasmon-polariton, which is a kind of oscillation that takes place in an exotic material such as the two-dimensional layered devices used in this research. Such materials "support elastic oscillations on its surface, really tightly confined" within the material, the team says. This process effectively shrinks the wavelengths of light by orders of magnitude, bringing it down "almost to the atomic scale."
Due to that shrinkage, the light can then be absorbed by the semiconductor, or emitted by it. In the graphene-based material, these properties can actually be controlled directly by simply varying a voltage applied to the graphene layer. In that way, "we can totally control the properties of the light, not just measure it," Kurman says.
Although the work is still at an early and theoretical stage, the researchers say that in principle this approach could lead to new kinds of solar cells capable of absorbing a wider range of light wavelengths, which would make the devices more efficient at converting sunlight to electricity. It could also lead to light-producing devices, such as lasers and LEDs, that could be tuned electronically to produce a wide range of colors. "This has a measure of tunability that's beyond what is currently available," Kaminer says.
"The work is very general," Kurman says, so the results should apply to many more cases than the specific ones used in this study. "We could use several other semiconductor materials, and some other light-matter polaritons." While this work was not done with silicon, it should be possible to apply the same principles to silicon-based devices, the team says. "By closing the momentum gap, we could introduce silicon into this world" of plasmon-based devices, Kurman says.